Synthesis of the C59N+ Carbocation. A Monomeric Azafullerene Isoelectronic to C60.
نویسندگان
چکیده
منابع مشابه
Spectromicroscopy of C60 and azafullerene C59N: Identifying surface adsorbed water
C60 fullerene crystals may serve as important catalysts for interstellar organic chemistry. To explore this possibility, the electronic structures of free-standing powders of C60 and (C59N)2 azafullerenes are characterized using X-ray microscopy with near-edge X-ray adsorption fine structure (NEXAFS) spectroscopy, closely coupled with density functional theory (DFT) calculations. This is suppor...
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School of Chemistry and Molecular Sciences University of Sussex, Brighton BN1 9QJ, UK Institute for Polymers and Organic Solids and Materials Research Laboratory, University of California, Santa Barbara, California 93106 IBM Research Division, Zurich Research Laboratory 8803 Rüschlikon, Switzerland; Scuola Normale Superiore, Piazza dei Cavalieri 7, 56126 Pisa, Italy European Synchrotron Radiati...
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The synthesis of azafullerene C59N is realized through a nitrogen plasma irradiation method, which is confirmed by the analysis of mass spectroscopy. A plasma consisting of a fullerene negative ion C60 and the azafullerene positive ion C59N��C60-C59N plasma��is generated by means of an electron beam ionization. C60 and C59N ions are selectively irradiated to single-walled carbon nanotubes (SWNT...
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chapter i provides an overview of structural linguistics and touches upon the saussurean dichotomies with the final goal of exploring their relevance to the stylistic studies of literature. to provide evidence for the singificance of the study, chapter ii deals with the controversial issue of linguistics and literature, and presents opposing views which, at the same time, have been central to t...
15 صفحه اولDoes a nitrogen matter? Synthesis and photoinduced electron transfer of perylenediimide donors covalently linked to C59N and C60 acceptors.
The first perylenediimide (PDI) covalently linked to an azafullerene (C59N) is described. PDI-C59N and PDI-C60 dyads where PDI acts as an electron-donor moiety have been synthesized by connection of the balls to the PDI 1-bay position. Photoexcitation of the PDI unit in both systems results in formation of the charge-separated state by photoinduced electron transfer from the singlet excited sta...
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ژورنال
عنوان ژورنال: ChemInform
سال: 2003
ISSN: 0931-7597,1522-2667
DOI: 10.1002/chin.200330127